57Fe ABSORPTION AND EMISSION SPECTROSCOPY IN SOME COBALT ACETYLACETONATE COMPLEXES [Co (acac)3, Co (acac)2, Co (acac)2·2H2O]
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چکیده
منابع مشابه
Evidence for cobalt-cobalt bond homolysis and wavelength-dependent CO loss in (μ2-alkyne)Co2(CO)6 complexes.
Time-resolved infrared spectroscopy was used to probe the photochemistry of three (μ(2)-alkyne)Co(2)(CO)(6) complexes. The data indicate the formation of a triplet diradical species, with lifetimes in the range 38-71 ps. Theoretical calculations support these experimental findings. No evidence for the CO loss species, (μ(2)-alkyne)Co(2)(CO)(5), was observed, and this is rationalized by the low ...
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ژورنال
عنوان ژورنال: Le Journal de Physique Colloques
سال: 1980
ISSN: 0449-1947
DOI: 10.1051/jphyscol:19801182